61. Stimuli-Responsive Magnetic Materials: Impact of Spin and Electronic Modulation, Kaushik, K.; Mehta, S.; Das, M.; Ghosh, S.; Kamilya, S.; Mondal A.* Chem. Comm. 2023, 59, 13107 DOI: 10.1039/D3CC04268E

60. Realizing the lowest bandgap and exciton binding energy in a two-dimensional lead halide system Pariari, D.; Mehta, S.; Mandal, S.; Mahata, A.; Pramanik, T.; Kamilya, S.; Vidhan, A.; Guru Row, T. N.; Santra, P.; Sarkar, S.; De A., F.; Mondal, A.; Sarma, D. D* J. Am. Chem. Soc.              2023, 145, 15896 DOI: 10.1021/jacs.3c03300

59. Spin-State Switching: Chemical Modulation and the Impact of Intermolecular Interactions in Manganese(III) Complexes, Bagchi, S.; Kamilya, S.; Mehta, S.; Mandal, S.; Bandyopadhyay, A.; Narayan, A.; Ghosh, S.; Mondal, A.* Dalton Trans. 2023, 52, 11335 DOI: 10.1039/D3DT01707A

58. Near Room Temperature Stepwise Spin State Switching and Photomagnetic Effect in a Mixed-Valence Molecular Square, Kamilya, S.; Mehta, S.; Lescouëzec, R.; Li, Y.; Pechousek, J.; Semwal, M.; Mondal A.* Dalton Trans. 2023, 52, 10700 DOI: 10.1039/D3DT01615C

57. Steric Effects on Spin States in a Series of Fe(III) Complexes, Dey, B.; Cirera, J.; Mehta, S.; Ferreira, L. P.; Arumugam, R.; Mondal, A.;* Martinho, P. N.;* Chandrasekhar V.* Cryst. Growth Des. 2023, 23, 6668 DOI: 10.1021/acs.cgd.3c00555

56. ON/OFF Photo(switching) along with Reversible Spin-State Change and Single-Crystal-to-Single-Crystal Transformation in a Mixed-Valence Fe(II)Fe(III) Molecular System, Kamilya, S.; Mehta, S.; Semwal, M.; Lescouëzec,* R.; Li, Y.; Pechousek, J.;* Reddy, V. R.; Riviere, E.; Rouzieres, M.; Mondal A.* Inorg. Chem. 2023, 62, 8794 DOI: 10.1021/acs.inorgchem.2c03972

55. Origin of the long-range ferrimagnetic ordering in cubic spinels, Das, A.; Pal, P.; Ranaut, D.; Islam, P. K.; Bhattacharya, G.; Mehta, S.; Mondal, A.; Adyam, V.; Mukherjee, K.; Das, A.; Choudhury, D.* Phys. Rev. B 2023, 107, L100414 DOI 10.1103/PhysRevB.107.L100414

54. Tuning of Dimensionality and Nuclearity as a Function of Ligand Field Modulation Resulting in Field-Induced Cobalt (II) Single-Ion Magnet, Hossain, S. M.; Kamilya, S.; Ghosh, S.; Herchel, R.; Kiskin, M. A.; Mehta, S.; Mondal, A.* Cryst. Growth Des. 2023, 23, 1656 DOI: 10.1021/acs.cgd.2c01255


53) Nickel substitution induced reentrant spin glass behavior in EuGa 4, Singh, A. K.; Panda, D. P.; Mehta, S.; Mondal, A.; Peter S. C.; Phys. Rev. B 2022, 106, 224414 DOI: 10.1103/PhysRevB.106.224414

52) Impact of Counteranion on Reversible Spin-State Switching in a Series of Cobalt (II) Complexes Containing a Redox-Active Ethylenedioxythiophene-Based Terpyridine Ligand: Ghosh, S.; Ghosh, S.; Kamilya, S.; Mandal, S.; Mehta, S.; Mondal A.*; Inorg. Chem. 2022, 61, 17080 DOI: 10.1021/acs.inorgchem.2c02313

51) Push and Pull Effect of Methoxy and Nitro Groups Modifies the Spin-State Switching Temperature in Fe (III) Complexes: Dey, B.; Mehta, S.; Mondal, A.; Cirera, J.; Colacio, E.; Chandrasekhar V.          ACS Omega 2022, 7, 39268 DOI: 10.1021/acsomega.2c05380

50) A bis-NHC–CAAC dimer derived dicationic diradical: Nayak, M. K.; Sarkar, P.; Elvers, B. J.; Mehta, S.; Zhang, F.; Chrysochos, N.; Krummenacher, I.; Vijayakanth, T.; Narayanan, R. S.; Dolai, R.; Roy, B.; Malik, V.; Rawat, H.; Mondal, A.*; Boomishankar, R.; Pati, S. K.; Braunschweig, H.; Schulzke, C.; Ravat, P.; Jana A.; Chem. Sci. 2022, 13, 12533 DOI: 10.1039/D2SC03937K

49) Tuning of Spin Crossover Properties in a Series of Mononuclear Cobalt(II) Complexes Based on Macrocyclic Tetradentate Ligand and Pseudohalide Coligands: Ghosh, S.; Selvamani, S.; Kamilya, S.; Mehta S.; Mondal, A*.; Dalton Trans. 2022, 51, 9642 DOI: 10.1039/D0DT02546A

48) LnIII (Ln = La, Gd, and Dy) Benzimidazolium Tricarboxylate Coordination Polymers with Hydrogen Bonding Modulated Magnetic Relaxation: Ramakant, G. A.; Ahmed, N.; Tarannum, I.; Mehta, S.; Nandeshwar, M.; Mondal, A.*; Singh, S. K.*, Prabusankar G. *; Cryst. Growth Des. 2022, Just Accepted, DOI: 10.1021/acs.cgd.2c00674

47) Effect of Ligand Chain Length for Tuning of Molecular Dimensionality and Magnetic Relaxation in Redox Active Cobalt(II) EDOT Complexes (EDOT = 3,4-Ethylenedioxythiophene: Ghosh, S.; Kamilya, S.; Mehta, S.; Herchel, R.; Kiskin, M.; Veber, S.; Fedin, M.; Mondal A.*; Chem.: Asian J., 2022, Just Accepted, DOI: 10.1002/asia.202200404R1

46) Impact of Counter Anions on Spin-State Switching of Manganese(III) Complexes Containing Azobenzene Ligand: Ghosh, S.; Bagchi, S.; Kamilya, S.; Mehta, S.; Sarkar, D.; Herchel R.; Mondal A.*; Dalton Trans. 2022, 51, 7681; DOI: 10.1039/D2DT00660J

45) Assembly of a sulfur-capped Strandberg type coordination polymer with copper: Synthesis, Structure, Magnetic and Catalytic studies: Gupta, Y.; Zaidi, Z.; Mehta, S.; Chandewar, P. R.; Rajput, N. S.; Paul, A. K.; Shee, D.; Mondal, A.; Gayatri, S. L.; Banerjee A. *; Dalton Trans. 2022, 51, 7255 DOI: 10.1039/D2DT00816E

44) Mycobactin Analogues with Excellent Pharmacokinetic Profile Demonstrate Potent Antitubercular Specific Activity and Exceptional Efflux Pump Inhibition: Shyam, M.; Verma, H.; Bhattacharje, G.; Mukherjee, P.; Singh, S.; Kamilya, S.; Jalani, P.; Das, S.; Dasgupta, A.; Mondal, A.; Das, A. K.; Singh, A.; Brucoli, F.; Bagnéris, C.; Dickman, R.; Basavanakatti, V. N.; Patibandla Babu, N.; Sankaran, V. Dev, A.; Sinha, B. N.; Bhakta, S.; Jayaprakash, V.; J. Med. Chem. 2022, 65, 234, DOI: 10.1021/acs.jmedchem.1c01349

43) Six coordinate dinuclear lanthanide(III) amide complexes: Investigation of magnetization Relaxation dynamics and their electronic structures: Rasamsetty, A., Mehta, S.; Ansari, K. U.; Kumar P.; Mondal A.*; Shanmugam, M.; Dalton Trans., 2022, 51, 63, DOI: 10.1039/D1DT03708K


42) Properties of [Fe4Cu2] magnetic cluster compound: Shukla, S.; Hossain, M. S.; Mehta, S.; Kamilya, S.; Mondal A., Sarma D D *; Bull. Mater. Sci. 2021, 44, 229, DOI: 10.1007/s12034-021-02518-y

41) Reversible Photo- and Thermo-Induced Spin-State Switching in a Heterometallic {5d-3d} W2Fe2 Molecular Square Complex: Kaushik, K.; Ghosh, S.; Kamilya, S.; Rouzières, M.; Mehta, S.; Mondal A.*; Inorg. Chem. 2021, 60, 7545; DOI: 10.1021/acs.inorgchem.1c01014

40) Thermo- and Photo-Induced Spin State Switching in an Iron(II) 2D Coordination Network associated with Large Light-Induced Thermal Hysteresis and Tuning of Dimensionality via Ligand Modulation: Ghosh, S.; Kamilya, S.; Pramanik, T.; Mohanty, A.; Rouzières, M.; Herchel, R.; Mehta, S.; Mondal A. *; Dalton Trans., 2021, DOI: 10.1039/D1DT00212K

39) Effect of Ligand Modulation on Metal-to-Metal Electron Transfer in a Series of [Fe2Co2] Molecular Square Complexes: Kamilya, S.; Ghosh, S.; Mehta, S.; Mondal A.*; J. Phys. Chem. A, 2021, DOI: 10.1021/acs.jpca.1c02032

38) Anionic Boron- and Carbon-Based Hetero-Diradicaloids Spanned by a p-Phenylene Bridge: Maiti, A.; Zhang, F.; Krummenacher, I.; Bhattacharyya, M.; Mehta, S.; Moos, M.; Lambert, C.; Engels, B.*; Mondal, A.*; Braunschweig, H.*; Ravat, P.; Jana A* J. Am. Chem. Soc., 2021, 143, 3687, DOI: 10.1021/jacs.0c12624

37) Effect of Ligand Substituent and Tuning the Spin-State Switching in Manganese(III) Complexes: Ghosh, S; Bagchi, S; Kamilya, S.; Mondal A * Dalton Trans., 2021, 50, 4634, DOI: 10.1039/D1DT00284H


36) Reversible Spin-State Switching and Tuning of Nuclearity and Dimensionality via Nonlinear Pseudohalides in Cobalt (II) Complexes: Ghosh, S.; Kamilya, S.; Rouzières, M.; Herchel, R.; Mehta, S.; Mondal A.* Inorg. Chem. 2020, 59, 17638, DOI:. 10.1021/acs.inorgchem.0c02887

35) Access to heteroleptic fluorido‐cyanido complexes with a large magnetic anisotropy by fluoride abstraction: Liu, J.‐L.; Pedersen, K. S.; Greer, S. M.; Oyarzabal, I.; Mondal, A.; Hill, S.; Wilhelm, F.; Rogalev, A.; Tressaud, A.; Durand, E.; Long, J. R.; Clérac R., Angew. Chem. Int. Ed. 2020, 59, 10306, DOI:.

34) Stepwise Spin-State Switching in a Manganese (III) Complex: Ghosh, S; Bagchi, S; Das, M.; Kamilya, S.; Mondal A * Dalton Trans., 2020, DOI:10.1039/D0DT02746D.

33) ON/OFF Photoswitching and Thermoinduced Spin Crossover with Cooperative Luminescence in a 2D Iron(II) Coordination Polymer: Ghosh, S.; Kamilya, S.; Pramanik, T.; Rouzières, M.; Herchel, R.; Mehta, S.; Mondal A. * Inorg. Chem. 2020, 59, 13009, DOI:.

32) Two-Step Thermo-Induced Metal-to-Metal Electron Transfer and ON/OFF Photo-Switch in a Molecular [Fe2Co2] Square Complex: Kamilya, S.; Ghosh, S.; Li, Y.; Dechambenoit, P.; Rouzieres, M.; Lescouezec, R.; Mehta, S.; Mondal, A. * Inorg. Chem., 2020, 59, 11879, DOI:. (FEATURED ARTICLE)

31) Reversible Thermo-Induced Spin Crossover in a Mononuclear cis-Dicyanamido-Cobalt(II) Complex Containing Macrocyclic Tetradentate Ligand: Ghosh, S.; Selvamani, S.; Mehta, S.; Mondal, A. * Dalton Trans., 2020, 49, 9208, DOI:.

30) Tuning of Spin Crossover Properties in a Series of Mononuclear Cobalt(II) Complexes Based on Macrocyclic Tetradentate Ligand and Pseudohalide Coligands: Ghosh, S.; Selvamani, S.; Kamilya, S.; Mehta S.; Mondal, A. * Dalton Trans., 2020, DOI:, DOI:. (HOT ARTICLE)

29) Effect of Coordination Geometry on Magnetic Properties in a Series of Cobalt(II) Complexes and Structural Transformation in Mother Liquor: Ghosh, S.; Kamilya, S.; Das, M.; Mehta, S.; Boulon, M.-E.; Nemec, I.; Rouzières, M.; Herchel, R.; Mondal, A. * Inorg. Chem. 2020, 59, 7067, DOI:.


28) Oxo-bridged trinuclear and tetranuclear manganese complexes supported with nitrogen donor ligands: syntheses, structures and properties: Bansal, D.; Mondal, A.; Lakshminarasimhan, N; Gupta R. Dalton Trans., 2019, 48, 7918, DOI:.

27) Probing the Local Magnetic Structure of the [FeIII(Tp)(CN)3]-Building Block Via Solid-State NMR Spectroscopy, Polarized Neutron Diffraction, and First-Principle Calculations: De, S.; Flambard, A.; Garnier, D.; Herson, P.; Köhler, F. H.; Mondal, A.; Costuas, K.; Gillon, B.; Lescouëzec, R.; Guennic, B. L.; Gendron F. Chem. Eur .J. 2019, 25,12120, DOI:.

26) Trinuclear and Hexanuclear Lanthanide (III) Complexes of the Chiral 3+ 3 Macrocycle: X-ray Crystal Structures and Magnetic Properties: Bereta, T.; Mondal, A.; Ślepokura, K.; Peng, Y.; Powell, A. K.; Lisowski J. Inorg. Chem. 2019, 58, 4201, DOI:.

25) Tetranuclear [(Fe2Fe2III)-Fe-II](2+) molecular switches:[Fe-II (bik)(2)(N-)(2)] spin-crossover complexes containing [Fe-III (Tp)(CN)(3)]() metalloligands as N-donor: Gamier, D.; Mondal, A.; Li, Y.; Herson, P.; Chamoreau, L.-M.; Toupet, L.; Cointe, M. B. Le; Moos, EMB; Breher, F.; Lescouezec R. Comptes Rendus Chimie 2019, 22, 516, DOI:.


24) Modulation of the spin-state of an iron(II) [2×2]-grid like complex by deprotonation of the hydrazone-based ligand: Dhers, S.; Mondal, A.; Aguila, D.; Ramirez, J.; Vela, S.; Dechambenoit, P.; Rouzieres, M.; Nitschke, J. R.; Clérac R.; Lehn. J.-M. J. Am. Chem. Soc. 2018, 140, 8218, DOI:.

23) Molecule-based microelectro-mechanical sensors: Urdampilleta, M.; Ayela, C.; Rosario-Amorin, D.; Mondal, A.; Rouzieres, M.; Dechambenoit, P.; Mathonière, C.; Ducrot, P. –H.; Dufour, I.; Mathieu, F.; Clérac R. Scientific Reports, 2018, 8, 8016, DOI:.


22) Elementary excitations in single-chain magnets: Lutz, P.; Aguilà, D.; Mondal, A.; Pinkowicz, D.; Marx, R.; Neugebauer, P.; Fak, B.; Ollivier, J.; Clérac, R.; van Slageren, J. Phys. Rev. B, 2017, 96, 094415, DOI:.

21) Heterometallic Heptanuclear [Cu5Ln2] (Ln = Tb, Dy, and Ho) Single-Molecule Magnets Organized in One-Dimensional Coordination Polymeric Network: Dey, A.; Das, S.; Kundu, S.; Mondal, A.; Rouzières, M; Mathonière, C.; Clérac, R.; Narayanan, R. S.; Chandrasekhar, V. Inorg. Chem. 2017, 56, 14612, DOI:.

20) Ambient-Stable Bis-Azoaromatic-Centered Diradical [(L•)M(L•)] Complexes of Rh (III): Synthesis, Structure, Redox, and Spin–Spin Interaction: Roy, S.; Pramanik, S.; Patra, S. C.; Adhikari, B.; Mondal, A.; Ganguly, S.; Pramanik, K. Inorg. Chem. 2017, 56, 12764, DOI:.

19) Hydroxide-Bridged Mixed-Valence Tetranuclear Cobalt 4-Nitrophenol Inclusion Complex Showing Single Molecule Magnet Property: Shankar, K.; Mondal, A.; Li, Y.; Journaux, Y.; Baruah, J. B. ChemistrySelect, 2017, 2, 7792, DOI:.

18) A new strongly paramagnetic cerium-containing microporous MOF for CO 2 fixation under ambient conditions: Das, S. K., Chatterjee, S.; Bhunia, S.; Mondal, A.; Mitra, P.; Kumari, V.; Pradhan, A.; Bhaumik, A. Dalton Trans. 2017, 46, 13783, DOI:.

17) Three novel mononuclear Mn(III) based single ion magnets with square pyramidal versus octahedral geometries: Dolai, M.; Mondal, A.; Liu, J.-L.; Ali, M. New J. Chem. 2017, 41, 10890, DOI:.


16) How far can the Anisotropy Deviate from Uniaxiality in a Dy-Based Single-Molecule Magnet? Dinuclear Dy(III) Complex Study: Baniodeh, A.; Mondal, A.; Galeev, R.; Sukhanov, A.; Eremina, R.; Voronkova, V.; Anson, C.; Powell, A. K. Appl Magn Reson, 2016, 48, 101, DOI:.

15) An {Fe60} tetrahedral cage: building nanoscopic molecular assemblies through cyanometallate and alkoxo linkers: Jiménez, J.‐R.; Mondal, A.; Chamoreau, L. M.; Fertey, P.; Tuna, F.; Julve, M.; Meunier, J. F.; Bousseksou, A.; Lescouëzec, R.; Lisnard, L. Dalton Trans. 2016, 45, 17610, DOI:  (Cover Picture).

14) A direct picture of the local magnetic anisotropy by polarized neutron diffraction (PND) confronted to EPR, magnetometry and ab initio investigations: Ridier, K.; Mondal, A.; Boilleau, C.; Cador, O.; Gillon, B.; Chaboussant, G.; Le Guennic, B.; Costuas, K.; Lescouëzec, R. Angew. Chem. Int. Ed. 2016, 55, 4101, DOI:  (Cover Picture).


13) Tetranuclear and Pentanuclear Compounds of Rare Earth Metals: Synthesis and Magnetism: Yadav, M.; Mondal, A.; Mereacre, V.; Jana, S. K.; Powell, A. K.; Roesky, P. W. Inorg. Chem. 2015, 54, 7846, DOI:.

12) Versatile Nano-platforms for Hybrid Systems: Revealing Spincrossover Behavior on Nanoparticles: Féré, A.; Ruyack, A. R.; Mondal, A.; Li, Y.; Lescouëzec, R.; Chaneac, C.; Fleury, B. J. Mater. Chem. C. 2015, 3, 3350, DOI:.

11) Mononuclear manganese (III) complexes of bidentate NO donor Schiff base ligands: synthesis, structural characterization, magnetic and catecholase studies: Dutta, A.; Biswas, S.; Dolai, M.; Shaw, B. K.; Mondal, A.; Saha, S. K.; Ali. M.; RSC Adv. 2015, 5, 23855, DOI:.

10) Structural and magnetic properties of hydroxyquinolinate clusters of cobalt (II) and manganese (II) and serendipitous intake of carbon dioxide during synthesis: Khakhlary, P.; Anson, C.; Mondal, A.; Powell, A. K.; Baruah, J. B. Dalton Trans. 2015, 44, 2964, DOI:.


9) Syntheses, structures, photoluminescence and magnetic properties of dicarboxylate coordination polymers of Mn, Co, Ni, Cu having N-(4-pyridylmethyl)-1,8-naphthalimide: Nath, J. K.; Mondal, A.; Powell, A. K.; Baruah, J. B. Cryst. Growth Des. 2014, 14, 4735, DOI:.

8) Photo and thermo-induced spin-transition in a cyanide-bridged {Mo2-Fe2} molecular square: Mondal, A.; Li, Y.; Chamoreau, L.-M.; Seuleiman, M.; Rechignat, L.; Bousseksou, A.; Boillot, M.-L.; Lescouëzec, R. Chem. Commun. 2014, 50, 2893, DOI:.


7) Surface chemistry on nanoparticles: Towards the exploration of synergistic phenomena between light and magnetism in hybrid molecular materials: Ruyack, A. R.; Fleury, B.; Mondal, A.; Li, Y.; Lescouëzec, R.; Chaneac, C.; Journaux, Y. Abstr. Pap. Am Chem. Soc. 2013, 245, 830-CHED, DOI:.

6) Combining Cyanometalates and Coordination Clusters: An Alternative Synthetic Route toward Original Molecular Materials: Mondal, A.; Dassie, P. I.; Chamoreau, L. M.; Journaux, Y.; Julve, M.; Lisnard, L.; Lescouëzec, R. Cryst. Growth Des. 2013, 13, 4190, DOI:.

5) W-Co discrete complex exhibiting Photo- and Thermo-Induced Magnetization: Mondal, A.; Chamoreau, L.-M.; Li, Y.; Journaux, Y.; Seuleiman, M.; Lescouëzec, R. Chem. Eur. J. 2013, 19, 7682, DOI:.

4) Cyanide and hydroxo-bridged nanocage: a new generation of coordination clusters: Mondal, A.; Durdevic, S.; Chamoreau, L.-M.; Journaux, Y.; Julve, M.; Lisnard, L.; Lescouëzec, R. Chem. Commun. 2013, 49, 1181, DOI:.

3) On/Off-Photoswitch in a Cyanide-bridged {Fe2Co2} Magnetic Molecular Square: Mondal, A.; Li, Y.; Seuleiman, M.; Julve, M.; Toupet, L.; Buron-Le Cointe, M.; Lescouëzec, R. J. Am. Chem. Soc. 2013, 135, 1653.


2) Photomagnetic effect in a cyanide-bridged mixed-valence {FeII2FeIII2} molecular square: Mondal, A.; Li, Y.; Herson, P.; Seuleiman, M.; Boillot, M. L.; Rivière, E.; Julve, M.; Rechignat, L.; Bousseksou, A.; Lescouëzec, R. Chem. Commun. 2012, 48, 5653, DOI:.


1) Binuclear terephthalato-bridged copper (II) complex with N2O2 coordinating tripodal ligand: synthesis, structure, magnetic properties and DFT study: Mondal, P.; Mondal, A.; Colacio, E.; Banerjee, A. J. Coord. Chem. 2010, 63, 1893, DOI:.




Title: Hybrid Halide perovskite-derived compounds, materials and method of preparation thereof

Patent No.: 419208

Application No.: 202241030552

Date of filing: 27/05/2022

Date of Award: 25/01/2023

Authors: Debasmita Pariari, Sakshi Mehta, Abhishake Mondal, D. D. Sarma